Aminoácidos como inibidores de corrosão do aço carbono em meios ácidos
DOI:
https://doi.org/10.33414/rtyc.54.80-92.2025Palavras-chave:
Aço SAE 1010, triptofano, ácido glutâmico, ácido aspártico, fenilalaninaResumo
A corrosão do aço em meios ácidos representa um desafio em várias indústrias, como petróleo e gás. Neste estudo, o potencial dos aminoácidos triptofano (TRP), ácido glutâmico (GLU), ácido aspártico (ASP) e fenilalanina (PHE) como inibidores de corrosão para aço SAE 1010 em uma solução de HCl 0,1 M foi investigado. Testes eletroquímicos, incluindo resistência à polarização linear, potencial de circuito aberto e curvas de polarização potenciodinâmica (Tafel), bem como análise de superfície por microscopia eletrônica de varredura (MEV) e espectroscopia de raios X por dispersão de energia (EDS), foram realizados. Os resultados revelaram que TRP, GLU e ASP exibiram propriedades inibitórias, com TRP apresentando uma eficiência de inibição de 72% a uma concentração de 1000 ppm. Em contraste, PHE não mostrou um efeito inibitório significativo. A análise SEM-EDS confirmou que TRP formou uma película protetora mais eficaz na superfície do aço.
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Alagbe, M., Umoru, L., Afonja, A., & Olorunniwo, O. E. (2009). Investigation of the effect of different amino‐acid derivatives on the inhibition of NST‐44 carbon steel corrosion in cassava fluid. Anti-Corrosion Methods and Materials, 56(1), 43-50. https://doi.org/10.1108/00035590910923455
Aouniti, A., Khaled, K. F., & Hammouti, B. (2013). Correlation Between Inhibition Efficiency and Chemical Structure of Some Amino Acids on the Corrosion of Armco Iron in Molar HCl. International Journal of Electrochemical Science, 8, 5925-5943. https://doi.org/10.1016/S1452-3981(23)14731-6
Askari, M., Aliofkhazraei, M., & Afroukhteh, Sahar. (2019). A comprehensive review on internal corrosion and cracking of oil and gas pipelines. Journal of Natural Gas Science and Engineering, 71, 102971. https://doi.org/10.1016/j.jngse.2019.102971
Byrne, C., Ramírez, M., Di Santo, E., Cristiano, N., Deyá, C., & D’Alessandro, O. (2021). Estudio de las propiedades anticorrosivas sobre acero SAE 1010 de extractos acuosos de romero (Rosmarinus officinalis), laurel (Laurus nobilis) y falso incienso (Plectranthus coleoides). Revista Materia, 26, 1-11. https://doi.org/10.1590/S1517-707620210003.13052
Cinitha, A., Umesha, P. K., & Iyer Nagesh R. (2014). An Overview of Corrosion and Experimental Studies on Corroded Mild Steel Compression Members. Journal of Civil Engineering, 18(6), 1735-1744. https://doi.org/10.1007/s12205-014-0362-0
D’Alessandro, O., Selmi, G., Byrne, C., Deyá, C., & Romagnoli R. (2018a). Tanino de Tara como precursor de un inhibidor de corrosión para acero SAE 1010. Revista de Ciencia y Tecnología, 30, 36-41. https://www.fceqyn.unam.edu.ar/recyt/index.php/recyt/article/view/11
D’Alessandro, O., Selmi, G., Byrne, C., Deyá, C., & Romagnoli, R. (2018b). Tanino de Quebracho colorado chaqueño (Schinopsis balansae) como precursor de un inhibidor de corrosión para acero de bajo contenido de carbono. Quebracho-Revista de Ciencias Forestales, 26, 31-39. https://www.redalyc.org/articulo.oa?id=48160748004
da Silva Moura, M., Bastos Vasques, R., Magalhães, S., Almeida Neto, F., de Lima Neto, P., dos Santos, L., Cerra Florez, M., Fargas Ribas, G., Santos Medeiros, S., Soares Salomão, F., Bedê Barros, E., & Silva Araújo, W. (2024). Assessment of the Amino Acid L-Histidine as a Corrosion Inhibitor for a 1018 Carbon Steel in Aqueous Sodium Chloride Solution. Crystals, 14(8), 703. https://doi.org/10.3390/cryst14080703
Dewangan, Y., Berdimurodov, E., & Verma, D. K. (2023). Chapter 1 - Amino acids: Classification, synthesis methods, reactions, and determination. En: C. Verma; D. K. Verma (Eds.), Handbook of Biomolecules (pp. 3-23). Elsevier. https://doi.org/10.1016/B978-0-323-91684-4.00015-3.
Eddy, N. O. (2011). Experimental and theoretical studies on some amino acids and their potential activity as inhibitors for the corrosion of mild steel, part 2. Journal of Advanced Research, 2(1), 35-47. https://doi.org/10.1016/j.jare.2010.08.005.
El Ibrahimi, B., Jmiai A., Bazzi, L., & El Issami, S. (2020). Amino acids and their derivatives as corrosion inhibitors for metals and alloys. Arabian Journal of Chemistry, 13(1), 740-771. https://doi.org/10.1016/j.arabjc.2017.07.013
Fontana, M. G. (1986). Corrosion engineering (3rd ed). McGraw-Hill, New York.
Fu, J., Li, S., Cao, I., Wang, Y., Yan, I., Lu, L. (2010). L-tryptophan as green corrosion inhibitor for low carbon steel in hydrochloric acid solution. Journal of Materials Science, 45, 979–986. https://doi.org/10.1007/s10853-009-4028-0
Guo, L., Ye, G., Bassey Obot, I., Li, X., Shen, X., Shi, W., & Zheng, X. (2017). Synergistic Effect of Potassium Iodide with L-Tryptophan on the Corrosion Inhibition of Mild Steel: A Combined Electrochemical and Theoretical Study. International Journal of Electrochemical Science, 12(1), 166-177. https://doi.org/10.20964/2017.01.04
Hamadi, L., Mansouri, S., Oulmi, K., & Kareche, A. (2018). The use of amino acids as corrosion inhibitors for metals: A review. Egyptian Journal of Petroleum, 27(4), 1157-1165. https://doi.org/10.1016/j.ejpe.2018.04.004
Hluchan, V., Wheeler B. L., & Hackerman N. (1988). Amino acids as corrosion inhibitors in hydrochloric acid solutions. Materials and corrosion, 39(11), 512-517. https://doi.org/10.1002/maco.19880391106
Huong, D. Q., Lan Huong, N. T., Anh Nguyet, T. T., Duong, T., Tuan, D., Thong, N. M., & Nam, P. C. (2020). Pivotal Role of Heteroatoms in Improving the Corrosion Inhibition Ability of Thiourea Derivatives. ACS omega, 5(42), 27655–27666. https://doi.org/10.1021/acsomega.0c04241
Kasprzhitskii, A., Lazorenko, G., Nazdracheva, T., & Yavna, V. (2021). Comparative Computational Study of L-Amino Acids as Green Corrosion Inhibitors for Mild Steel. Computation, 9(1), 1. https://doi.org/10.3390/computation9010001
McCafferty, E. (2005). Validation of corrosion rates measured by the Tafel extrapolation method. Corrosion Science, 47(12), 3202-3215. https://doi.org/10.1016/j.corsci.2005.05.046
Mobin, M., Parveen, M., & Khan, M. A. (2011). Inhibition of Mild Steel Corrosion Using L-tryptophan and Synergistic Surfactant Additives. Port. Electrochim. Acta, 29(6), 391-403. https://doi.org/10.4152/pea.201106391
Oguzie, E. E., Li, Y., Wang, S. G., & Wang, F. (2011). Understanding corrosion inhibition mechanisms—Experimental and theoretical approach. RSC Advances, 1(5), 866. https://doi.org/10.1039/c1ra00148e
Olivares, O., Likhanova, N.V., Gómez, B., Navarrete, J., Llanos-Serrano, M., Arce, E., & Hallen, J. (2006). Electrochemical and XPS studies of decyl amides of α-amino acids adsorption on carbon steel in acidic environment. Applied Surface Science, 252(8), 2894-2909. https://doi.org/10.1016/j.apsusc.2005.04.040
Popoola, L. T. (2019). Organic green corrosion inhibitors (OGCIs): a critical review. Corrosion Reviews, 37(2), 71-102. https://doi.org/10.1515/corrrev-2018-0058
Pour-Ali, S., Tavangar, R., & Hejazi, S. (2023). Comprehensive assessment of some l-amino acids as eco-friendly corrosion inhibitors for mild steel in HCl: Insights from experimental and theoretical studies. Journal of Physics and Chemistry of Solids, 181, 111550. https://doi.org/10.1016/j.jpcs.2023.111550
Radovanović, M., Petrović Mihajlović, M., Tasić, Ž., Simonović, A., & Antonijević, M. (2021). Inhibitory effect of L-Threonine and L-Lysine and influence of surfactant on stainless steel corrosion in artificial body solution. Journal of Molecular Liquids, 342, 116939. https://doi.org/10.1016/j.molliq.2021.116939
Roscher, J., Liu, D., Xie, X., & Holze, R. (2024). Aromatic Metal Corrosion Inhibitors. Corrosion and Materials Degradation, 5(4), 513-560. https://doi.org/10.3390/cmd5040024
Singh, A., & Ebenso, E. E. (2013). Use of Glutamine as a New and Effective Corrosion Inhibitor for Mild Steel in 1 M HCl Solution. Int. J. Electrochem. Sci., 8(12), 12874-12883. https://doi.org/10.1016/S1452-3981(23)13313-X
Wasim, M., & Djukic, M. B. (2022). External corrosion of oil and gas pipelines: A review of failure mechanisms and predictive preventions. Journal of Natural Gas Science and Engineering, 100, 104467. http://doi.org/10.1016/j.jngse.2022.104467
Yadav, M., Sarkar, T. K., & Purkait, T. (2015). Amino acid compounds as eco-friendly corrosion inhibitor for N80 steel in HCl solution: Electrochemical and theoretical approaches. Journal of Molecular Liquids, 212, 731-738. http://dx.doi.org/10.1016/j.molliq.2015.10.021
Zerfaoui, M., Oudda, H., Hammouti, B., Kertit, S., & Benkaddour, M. (2004). Inhibition of corrosion of iron in citric acid media by aminoacids, Prog. Org. Coat., 51(2), 134-138. https://doi.org/10.1016/j.porgcoat.2004.05.005
Zhang, H., & Lan, H. (2017). A review of internal corrosion mechanism and experimental study for pipelines based on multiphase flow. Corrosion Reviews, 35(6), 425-444. https://doi.org/10.1515/corrrev-2017-0064
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Copyright (c) 2025 Christian Byrne, Santino Mariano Toro, Nicole Rocío Uviedo Barone , Oriana D’Alessandro

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